Sometimes the outcomes are not equally likely, so you can't just count cases. A bent coin, a drawing pin or a weighted spinner has no obvious symmetry to lean on. When that happens, you estimate the probability by running the experiment many times and watching how often the outcome shows up — its relative frequency.
The more trials you run, the closer this fraction settles towards the true probability. A few throws tell you little; thousands tell you a lot.
Here are the results of spinning a coloured spinner 50 times. Each bar is a count; divide by the total to estimate the probability of that colour.
For example, red came up