When two straight lines cross, they make four angles at the meeting point. The two angles directly across from each other — sharing only the crossing point, opening in opposite directions — are called vertically opposite angles (or just "vertical angles"). The surprise is that they are always exactly equal.
It follows from one fact you already know:
No measuring needed — two straight lines do all the work. Step through the reason.
The same argument works for the other pair, giving
Two lines cross. Fill in every angle you can — using vertically opposite angles and angles on a straight line — ending with the highlighted one. Refresh for a new figure; Check explains each step.